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:2005-06-13;:2005-09-06:(NCEF-04-1006);(200136):(1978-),,,.:1001-2060(2006)02-0111-04,,(,430033):,()(()),,:;;;;:O414.1:A1,,,,[1],20,,,,,,,,,,30,[26],,,2Berry[7],,(generalizedformalism)Tsirlin[8],,,(),,,,;Tsirlin21220063JOURNALOFENGINEERINGFORTHERMALENERGYANDPOWERVol.21,No.2Mar.,200621120063112,:SO2SO2,16.7%Mansson[25],,,5,,,,:;;:[1]FONYOZ.Thermodynamicanalysisofrec2tification.Reversiblemodelofrectifica2tion[J].IntChemEng,1974,14(1):18-27.[2]BEJANA.Entropygenerationminimiza2tion:thenewthermodynamicsoffinite2sizedeviceandfinite2timeprocesses[J].JAp2plPhys,1996,79(3):1191-1218.[3],,WuChih.[J].,1998,18(4):62-89.[4]CHENL,SUNF,WUC.Finitetimether2modynamicsoptimizationorentropygener2ationminimizationofenergysystems[J].JNon2EquilibThermodyn,1999,24(3):327-359.[5]CHENL,SUNF.Advancesinfinitetimethermodynamics:analysisandoptimization[M].NewYork:NovaSciencePublishers,2004.[6].[M].:,2005.[7]ORLOVVN,BERRYRS.Estimationofminimalmeatconsumptionforheat2drivenseparationprocessesviamethodsoffinite2timethermodynamics[J].JPhysChem,1991,95(14):5624-5628.[8]MIRONOVAVA,TSIRLINAM,KAZA2KOVVA,etal.Finite2timethermodynam2ics:exergyandoptimizationoftime2con2strainedprocesses[J].JApplPhys,1994,76(2):629-636.[9]BERRYRS,KAZAKOVVA,SIENIUTY2CZS,etal.Thermodynamicoptimizationoffinite2timeprocesses[M].Chichester:JohnWiley&SonsLtd,2000.[10].[D].:,2004.[11]SALAMONP,NULTONJD.Thegeome2tryofseparationprocesses:ahorse2carrottheoremforsteadyflowsystems[J].Eu2rophysLett,1998,42(5):571-576.[12]GOFFPL,CACHOTT,RENAUDINV,etal.Finitetimechemicalthermodynamics[J].Entropie,2000,36(224/225):26-31.[13]MUSLIMHA,DINCERI,ZUBAIRSM.Effectofreferencestateonexergyefficien2ciesofone2andtwo2stagecrudeoildistilla2tionplants[J].IntJThermalSciences,2005,44(1):65-73.[14]BANDYOPADHYAYS,MISHRAM,SHENOYUV.Energy2basedtargetsformultiple2feeddistillationcolumns[J].JAIChE,2004,50(8):1837-1853.[15]MULLINSOC,BERRYRS.Optimiza2tionofentropyproductionindistillation[J].JPhysChem,1984,88(4):723-728.[16]CERCIY.Theminimumworkrequirementfordistillationprocesses[J].ExergyTheIntJ,2002,2(1):15-23.[17]SAUARE,SIRAGUSAG,ANDRESSENB.Equalthermodynamicdistanceande2quipartitionofforcesprinciplesappliedtobinarydistillation[J].JPhysChem,2001,105(11):2312-2320.[18]SCHALLERM,HOFFMANNKH,RIVEROR,etal.Theinfluenceofheattransferirreversibilitiesontheoptimalper2formanceofdiabaticdistillationcolumns[J].JNon2EquilibThermodyn,2002,27(3):257-269.[19]KOEIJERGD,ROSJORDEA,KJEL2STRUPS.Distributionofheatexchangeinoptimumdiabaticdistillationcolumns[J].EnergyTheIntJ,2004,29(12/15):2425-2440.[20]RIVEROR.Exergysimulationandopti2mizationofadiabaticanddiabaticbinarydistillation[J].EnergyTheIntJ,2001,26(5):561-593.[21],,.[A].[C].:,2005.856-861.[22]SCHONJC,ANDRESENB.Multiplemodesfortheoperationofabinarydistilla2tioncolumn[J].IndEngChemRes,1996,35(7):2327-2333.[23]NULTONJD,SALAMONP.Finite2timethermodynamicanalysisofcontrolledheatintegration[R].ProcECOS1998,1998.[24]JOHANNESSENE.Thestateofminimumentropyproductioninanoptimallycon2trolledsystem[D].Norway:NorwegianUni2versityofScienceandTechnology,2004.[25]MANSSONB,ANDRESENB.Optimaltemperatureprofileforanammoniareactor[J].IndEngChemProcessDesiDeve,1986,25(1):59-65.()4112006=Finite2timeThermodynamicOptimizationofHeatandMassTransferProcessandRelevantEquipment[,]/SHULi2wei,CHENLin2gen,SUNFeng2rui(PostgraduateCol2legeundertheNavalEngineeringUniversity,Wuhan,China,PostCode:430033)//JournalofEngineeringforThermalEnergy&Power.-2006,21(2).-111114Theimportantsignificanceoffinite2timethermodynamicoptimizationtoaheatandmasstransferprocessandrelevante2quipmenthasbeenexpounded.Fromthestandpointofphysicsandengineeringabroadoverviewisgivenofthepresentstatusofresearchintheabove2mentionedarena.Withfocusedattentionadescriptionisgivenoftheperformanceopti2mizationoftheoreticalandengineeringcycleconcerningdistillationandseparationprocessesaswellastheperformanceoptimizationofchemicalreactorsfromthefollowingaspects:optimizationmethods(numericaloptimizationandoptimalcontroltheory),optimizationobjectives(minimumentropygeneration,minimumaverageheat(work)consumption,max2imumproductivity,maximumexergyefficiency)andoptimizationresults.Alsoexploredisthedevelopmenttrendofthethermodynamicoptimizationoftheheatandmasstransferprocessandrelevantequipment.Itisnotedthatthemajorde2velopmentdirectionofthecurrentnon2adiabaticdistillationthermodynamicoptimizationconsistsinthenon2adiabaticdis2tillationequippedwithcompletelycontrollableheatexchangers,sequentialheatexchangersandheatexchangernetworkincorporatingheatengines.Keywords:finite2timethermodynamics,optimization,heatandmasstransferprocess,non2adiabaticdistillation,chemicalreactorNOx=TheImpactofSeveralFactorsofHigh2temperatureAirCom2bustiononNOxGenerationQuantity[,]/ZHANGFu2bao,LUOYong2hao,HULi2yuan,etal(CollegeofMe2chanical&PowerEngineeringundertheShanghaiJiaotongUniversity,Shanghai,China,PostCode:200240)//JournalofEngineeringforThermalEnergy&Power.-2006,21(2).-115118NOxproducedinlargequantitiesbyindustrialproductionprocessesisakindofimportantsubstance,whichcanleadto