TPS及TPO类热塑性弹性体

36820098WorldRubberIndustryVo.l36No.8:27~32Aug.2009TPSTPO张勇1,张虹2(1.辽宁省阜新市封闭母线有限公司,辽宁阜新123000;2.辽宁省阜新市橡胶厂,辽宁阜新123000)编译:较详细地阐述了日本各类热塑性弹性体的生产和销售情况及实际应用现状,重点介绍了6个大类:TPSTPOTPVCTPUTPEETPAE:热塑性弹性体;改性;软段;硬段;聚合物:TQ334:B:16718232(2009)080027060前言(TPE),,,;TPE:(1)(TPS);(2)(TPO);(3)(TPVC);(4)(TPU);(5)(TPEE);(6)(TPAE);(7),TPE8%~10%,TPO(TPV)TPS(SEBSSEPS),,TPE,TPE,,/,,TPSTPO,,,TPE,TPE,TPE,,,,,1TPE,2TPETPE,TPSTPO1TPETPSTPOTPVC()TPUTPEETPAEPA6,1各种TPE的基本原料和应用范围1.1TPS2TPETPSTPOTPVCTPUTPEETPAE,,,PP,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,PPPSPPE,PVCABSPOMPVC,1.1.1TPSTPE,TPS,,,,PS()PP()SBS,SIS,SBS,SIS,TPS,SIS,,,SIS,!∀SIS,TPSPPPSPPE(),TPS,TPS,,SEBSSEPSHSBR,SEBSSEPS(),,,,PP,PPSIS#∃%JSR()&∋((HSBR)!)∗∀(SEBS),SEBSPP/,PPJSRCEBCSEBC,TPSC!28!2009,LLDPE,PE,LLDPEPEPPPSTPSPSPC()PBT()PPE()TPU,,SBSSBBS,SEBS,∀,,SBBS,,,,(+,+)SIBSTAR,,,,1.1.2TPSSEBSSEPSSEEPS(SIBS)PP,TPSTPSPPTPV(),TPSPSPP,,TPOTPS,PPE();,,TPS,,,PET(),OA,,TPS,,TPSSEBSSEPSTPSPP,KraiburgTPSTPVTPUTPS1.1.3TPSTPSTPSSEBSSEPSSEEPS,,TPSSEEPS,,,,,−.A,/,,TPSHSBR(),SIESS,TPS,SEBSPP,,SEBS1.2TPOTPO31.2.1TPOTPOPPPE,EPDMEPMTPETPO()TPV,,!29!368,.TPSTPOTPO70%,TPOTPVTPVEPPP/EPDMPP/NBRPP/NRPE/EPDM/PPIIR/PPTPS/PP,PPEPDM,,,,,,1.2.2TPOTPOEPMPO(),PPTPO40%~50%,PP5%~20%(),TPO1.2.3,/01!)2,JSREBMEPR33/(g/cm3)!)2!)2A0.885!)2P0.870!)2XR0.891!)2BL0.900~0.915#,;∃,,;%,;&,;∋PEPP,()!)2XM,XR,,25(~35(,,3011(EOM)0.857~0.910#,;∃,;%,;&PP,TPO,EPDM1(EBM)0.857~0.905#,;∃,,;%,,!)2XM,∀!)2XR,,,,,4∗5,,PP,!30!2009Infuse(OBC),(120()(100()OBCTg(),,,PP∀!)6−,PP,PP,,1.3TPVCTPVC#PVC∃,TPVC,TPU,TPO,TPVC,TPVC,,VCT,PVC/NBRTPV/PVCTPU/PVCPVC/EVAgPVC,,PVC,,1.4TPUTPU[TDI()MDI()HDI()][PTMG()PPG()]()TPETPUTPETPU,,TDITPU,HDI,,OA,,TPUTPUTPU,,,,,TPUSEBS,1.5TPEETPEEPBT,PTMGPPG()TPE,TPEETPEE,#.−7879−,9:2(TPEE,TPS,TPEE,ETPVETPVTPEE,TPEE,TPEE50%,60~70(A),150(,TPE,TPEE,1.6TPAETPAEPA6PA12PA66PA11PTMGPPG,!31!368,.TPSTPO,TPAE,OA,,4TPAE,,VTR()MD()DVD,TPAE2展望,TPE,,TPO,TPETPE,:#TPE;∃;%;&;∋;)#,∃PE,,%ETPVSuperTPVTPU/TPS,,TPV,SuperTPVTPEE,,,PA6TPV,TPEEHSBRTPV,%&∋),TPSTPSTPS,SBSSEBS,SEPSTPSPET/PP/PCPP/PMMA/TPU,TPV,(TPE),,TPS,,3结语TPE,,TPE,TPE,TPETPE,:[1]./%;.2TPSTPO=[J].?≅,2007,80(6):226232.[2]藥./%;.2ΑΒΧΔ[M].:,2003.[:]:20080906!32!2009