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:2007-09-11:(1979-),,,,.21Vo12,No120083MATERIALSRESEARCHANDAPPLICATIONMar2008:16739981(2008)01000605殷焕顺,艾仕云,钱萍,汪建民(,271018):,.:;;;:TQ4268:A,,.,,.1,,..11.,Ag+Ag,.,,.,.[1](CTSG),.(01mol/L)61CTSG04g40,30~40nm.,..Raveendran[2],D,..Sun[3],.12,.HanMinghan[4]Ag+TiO2,Ag/TiO2,TiO210nm.Li[5](),,,.Zhou[6],,.13,.ZhuJJ[7],EDTAAgNO3.3050Hz100W,,40nm6m;-03V(SCE),80nm15m.[89]NN,N,N,.,,.,EDTA,AgNO3.,10mAAgNO3,(1g013g)[10].14,..[11]NdYAG1064nm,,5~20nm.25min,5~35nm.,,.TsujiTakeshi[12]800nm,.,,.,,.15..[13],/Al2O3.,Al/Al2O3.[14](Al2O3/Al),5m25nm,Al2O3/Al,.(SAED),(FCC).16,,..[15]005mol/LAgNO3,7104Co60,10nm,.Zhu[16],8nm.[17],(PVA),,.17,(CMC),,.()()4.,10~20nm..,(OPW)(WPO),WPO.[18](SDS),.,20~30nm.Rong[19],,NaBH4.,,.18,,.721,:,.[20]NaBH4AgNO3,(42)nm.,3mL1mmol/L2mmol/L(Mw=58000),15W(=25317nm)48h,50~120nm50m.[21],,,,.221,.().,.,,.,,.[22]Ag.21%,9919%,,.,.,.[23]LDPE,,40~70nm,Ag+..[24].,;,,,.,,.,,.,.22.HanMinghan[4]TiO2.,TiO2Ag/TiO2Se().TiO2,Se()Se,SeH2SeSe2-.Ag/TiO2,Se()Se,H2Se,pH=315.Se,SeH2Se.Li[25]Ag/HZSMSCH4NO,7%,NO.,CH4NO.,,,;,,.,,.23.,.[26]AgNO3,,.1010-6~1510-2mol/L,12s,.[27].(BCB),82008BCB4010-7~2110-4mol/L,1510-8mol/L.,[28].pH=60,,5010-7~4010-4mol/L,413710-8mol/L.,.24.DNADNA,DNA.,.RPVanDuyne[29]:,,,.,.JWang[30]DNA:DNA,,20nm,,HBrBr2,DNA.10L(20min)10pmolDNA.,DNA.,DNA,.25(SERS)[31],SERS.,SERS,SERS.,,,,.3,.,,.,.,,,.:[1],,,.[J].,2006,35(9):2629[2]RAVEENDRANP,FUJ,WALLENSLCompletelygreensynthesisandstabilizationofmetalnanoparticles[J].JournaloftheAmericanChemicalSociety,2003,125:1394013941[3]SUNX,LIYColloidalcarbonspheresandtheircore/shellstructureswithnoblemetalnanoparticles[J].AngewandteChemieInternationalEdition,2004,43(5):597601[4]HANMH,LINHF,YUANYH,etalPressuredropfortwophasecountercurrentflowinapackedcolumnwithanovelinternal[J].ChemicalEngineeringJournal,2003,94(3):171260[5]LIHX,LINMZ,HOUJGElectrophoreticdepositionofligandstabilizedsilvernanoparticlessynthesizedbytheprocessofphotochemicalreduction[J].JournalofCrystalGrowth,2000,212:222226[6]ZHOUY,YUSH,WANGCY,etalAnovelultravioletirradiationphotoreductiontechniqueforthepreparationofsinglecrystalAgnanorodsandAgdendrites[J].AdvancedMaterials,1999,11(10):850852921,:[7]ZHUJJ,QIUQF,WANGH,etalSynthesisofsilvernanowiresbyasonoelectrochemicalmethod[J].InorganicChemistryCommunications,2002,5(3):242244[8],.[J].,2001,21(5):5859[9],,,.[J].:,2002,38(1):119123[10],,,.[J].,2006,12(21):18371839[11],,.[J].,2003,14(4):383386[12]TSUJIT,KAKITAT,TSUJIMPreparationofnanosizeparticlesofsilverwithfemtosecondlaserablationinwater[J].AppliedSurfaceScience,2003,206(14):314320[13],,,.Al2O3[J].,2001,17(2):116118[14],,,.TEM[J].,2002,18(6):532535[15],,,.[J].,1996(1):4445[16]ZHUYJ,QIANYT,ZHANGMW,etalPreparationofnanocrystallinesilverpowdersbyrayradiationcombinedwithhydrothermaltreatment[J].MaterialsLetters,1993,17:314318[17],,,.[J].,2004,24(3):6972[18],,,.[J].,2004,32(2):208211[19]RONGM,ZHANGM,LIUHSynthesisofsilvernanoparticlesandtheirselforganizationbehaviorinepoxyresin[J].Polymer,1999,40:61696178[20],,,.[J].,2004,62(18):17711774[21],,,.[J].,2005,16(4):5254[22],.[J].,2002,35(1):912[23],,,.PE/[J].,2002,23(2):129132[24],,,.[J].,2006,27(5):135137[25]LIZ,MARIAFSOnthepromotionofAgZSM5byceriumfortheSCRofnobymethane[J].JournalofCatalysis,1999,182:313327[26],,,.Ag[J].,2005,24(2):3234[27],,,.[J].,2004,23(12):7881[28],,,.[J].,2005,41(5):305308[29]JENSENTR,MALINSKYD,HAYNESCL,etal.Nanospherelithography:tunablelocalizedsurfaceplasmonresonancespectraofsilvernanoparticles[J].JournalofPhysicalChemistryB,2000,104:1054910556[30]WANGJ,POLSKYR,XUDSilverenhancedcolloidalgoldelectrochemicalstrippingdetectionofDNAhybridization[J].Langmuir,2001,17(19):57395741[31],,.[J].,2001,14(4):465468PreparationmethodsandapplicationofsilvernanomaterialYINHuanshun,AIShiyun,QIANPing,WANGJianmin(CollegeofChemistryandMaterialScience,ShandongAgricultureUniversity,Taian271018,China)Abstract:Preparationofsilvernanomaterialhasbeenthemostactivefieldinthemetalnanometermaterialsduetoitsuniqueapplicationinrecentyears.Inthispaper,recentresearchadvancesinthepreparationmethodsofsilvernanomaterial,suchaschemicalreduction,photochemicalmethod,electrochemicalmethod,laserablation,chemicalelectroplate,microemulsionmethodandradiantmethodarepresented.TheapplicationsofnanosilverarealsoprospectedKeywords:nanomaterial;silver;preparation;application102008