人教版高中化学选修三测试题及答案全套

143(15)1.()ABCD2.()ABCD3.()A6sB4pC3dD4f4.21s22s22p63s23p6()ABBBCDA5.()AKLMNBspdfCpxpypzD6.()AHLiNaKBIBrClFCNaMgAlSiDSiAlMgNa7.ABAB2AB()Ans2ns2np4Bns1ns2np4Cns2ns2np5Dns1ns28.()A18B16C8D69.4f75d16s2()ABBBCBDB10.3d4s3()ASBFeCSiDCl11.1s22s22p63s21s22s22p63p2()ABCpD12.RTQWT()ARWBQWCTQRDT13.()A3p1s22s22p63s23p2BMN4s21s22s22p63s23p63d64s2C4s24p5D2p2s22p514.()ABCD15.()A5sB2pC3dD4s(3)16.(1)(Au)CuAu________(2)[Ar]3d104s24p1________________(3)A________________17.XKLMNX________________18.ABCDEABCDEA2CCD24ED(1)ABCDE________________________________________________________________________(2)________________________________________________________________________1.A2.CAAr(Li)r(S)r(Cl)3.D4.D4s2A5.Csppxpypzp6.AABACD7.CAB2A2ABAA2ns2BA7ns2np58.B2,8,()826,28616,169.D64f75d16s2fB10.B3d4s33d2362886226Fe11.A12.DTAlQSiWSRNNH3H2SAH2SiO3H2SO4BAlCl3NaAlO2D13.BA3p3p21s22s22p63s23p2BMN4s21s22s22p63s23p63d104s2C152s22p132102s22p683153s23p354204s225254s226304s227354s22p57D2p2p152s22p12s22p514.CC15.A1s2s2p3s3p4s3d4p5s4d5p6s4f5s16.(1)5d106s1(2)A(3)4s24p3(1)Cu29[Ar]3d104s1AuCuAu5d106s1(2)A(3)4s24p33317.CaXMNKL10M8N2Ca18.(1)ABCDE(2)A2s22p2B2s22p3C2s22p4D3s23p4E3s23p5A21s22s22p2ACCD24CDCODSBACBNEDEClA2s22p2B2s22p3C2s22p4D3s23p4E3s23p53(15)1.NH3ANH3B3NHCNH33NH3107.3DNH33NH31202.sp3p()PF3CCl4NH3H2OABCD3.()ABCD4.N2OCO2N2OAN2OCO2BN2OH2OCN2ONH3DN2O5.()ABA(H)ACHOH180DHO463kJ/mol18gH2OH2O22463kJ6.ANH5()ANH5BNH5NH3C1molNH55molNHDNH57.()ABCD8.()ABCNH4NO3H2SO4D9.B3N3H6ABC3DKMnO410.XY()AXY4BXY3CXY2DXY11.()1mol()P4O6(kJmol1)PP198PO360O=O498P4()3O2=P4O6()A-1638kJmol-1B1638kJmol1C126kJmol1D126kJmol112.sAN23H22NH3B2C2H25O22H2O4CO2CCl2H2HClDC2H4H2C2H613.()ANa2OBNaOHCCaBr2DHF14.()ACH460BCH3OPCl3DB3N3H6B3N3H615.ACH4NH4+60BB3N3H61molB3N3H66molCNH3PCl3DBF3CO32(3)16.AG12___________34V__________________________________________5__________________________617.1FeSCN2+[CuNH34]2+2H3O+VSEPRBCl33sp3V18.________(3)19.XYZXZY1Y___________Z___________2Y___________3XY_________X20.ABCD182,3,4,6AC11BD12D(1)ABCD________()(2)AHF_____________________________(3)B________________(B________((4)AB________()AXBYHXO________HXO3________HXO4H2YO3________H2YO4(5)D________________________21.XYZXYYZYpXp2YX2ZX2(1)Z________(2)YX2________________1.CANH3NH3BNHDCNH3C2.APF3Psp33sp33Fp1CCl4C4sp34ClpNH3Nsp33sp33Hs1H2OOsp32sp32Hs2A3.AABN2CH2ONaOHNa2O2H2O2D4.DN2OCO2CO2N2OH2OVNH35.BDHO463kJ/mol1molHO1molHO463kJ,18gH2O1molH2O2molHO2463kJH2O2HHO===ODLi1.0I2.51.51.7LiIB6.CNH5NH4HNH4HNH37.C8.DABDNH4NO3H2SO4NHSOC9.CAABBCBNCDKMnO4D10.DXY11.A1molP43molO21molP4O61molP46molPP3molO23molO===O1molP4O612molPOH(198kJmol16498kJmol13)360kJmol1121638kJmol112.CspsspN2spAO2Cl2H2sABCDC2H2spBC2H4spD13.BOHNaOH14.BCH410928ABH3OPCl3CB3N3H6D15.DACH4NH4+58BB3N3H61230B3N3H6CNH3PCl34NH38PCl326DBF3CO32424BF33Bsp216.1H2N2O2Cl22HClCONO3HCNCO2N2O4H2O5NaOH6Na2O2AHBCCNDOENaFAlGCl17.1Fe3+23CH4CF4NH3NF3VH2O12VSEPR3sp344V4218.735219.(1)P4H2263sp3NH3(1)YXZXZ(2)3606(3)2X3H2X3XPH3PH3Psp3HPH10928PH3PH3PH3NH320.(1)NOClS(2)HFHCl(3)V(4)HClO4H2SO4(5)sp32CO18ABCDHClH2SH2O2N2H4(1)ClSONNOClS(2)AHClHFHClHFHCl(3)BH2SH2OH2OOsp3VH2SV(4)ABClSHClO4H2SO4ClSHClO4H2SO4XYHClO21.(1)1s22s22p63s23p2(2)22Xp2p4XXYpYXYXYZZSiCO2O===C===O223(15)1.ABCD2.SbCl3SbCl5()ASbCl3SbCl5SbCl3SbCl5BSbCl3SbCl573.52.8SbCl3SbCl5CSbCl3SbCl5AgNO3SbCl3SbCl5DSbCl3SbCl5SbCl3SbCl53.ABBa2O2CNaClDBa2+Ba2+124.ANaFMgF2AlF3BNaFNaClNaBrCCsClNaClCaF2DMgOCaOBaO5.()AMgAlCaBAlNaLiCAlMgCaDMgBaAl6.()SiCNaFNaClH2OH2SCaTiO3()Ti412O2SiO2ABCD7.NaINaI1.01.5nm0.28nm()ANaIBCNaID8.A1B2C3D49.()AABBCCDD10.()ABCD11.ASiO12B8C12DSiO812.(BN)()ABCD13.()ABCD14.LaNiALaNi5BLaNiCLa14Ni24DLa7Ni1215.ABABABAB()AABBCD(3)16.()8dNAM(1)________(2)_______________(3)____________(4)____________17.I(1)________C(2)CCC____________(3)ngC____________(4)IIC______18.(3)19.QRXYZ20QXRQYZArYZ1Q_____________2R(X3XX2H44QYZ______________________________QY_____________20.XY1YXXY2XX32X1YXYX4Mgmol1gcm3NAXcm21.ABCDEFAB6DL2EFE(1)EDF____________()________________________________________________________________________(2)C________________________________________________________________________(3)1molB2A2____________(4)()B_____________(5)E_________8______(6)BD2()__________(B__________(1)SiO2SiCl4SiCl4(2)NH3(3)3NA(1.8061024)(4)8(5)3(6)sp3(1)SiO2SiCl4SiO2SiCl4SiO2SiCl4(2)CNH3NH3NH3(3)22.X360pm49.0g/cm3(1)(2)(3)(4)(pm)23.(1)NiONaClNi2+O2-10-8cmNiONiO74.7gmol-1(2)NiONi2+Ni2+Ni3+NiONi0.97ONi3+Ni2+24.198619871YCuBaO21CuCu