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乌洛托品化学品安全技术说明书(MSDS)化学品名称：ChemicalProduct：化学品中文名称：六亚甲基四胺ChemicalChineseName：六亚甲基四胺化学品英文名称：hexamethylenetetramineChemicalEnglishName：hexamethylenetetramine分子式：C6H12N4MolecularFormula：C6H12N4分子量：140.18MolecularWeight：140.18成分/组成信息：Composition，InformationonIngredients：主要成分：纯品KeyComponent：Technical-pureGradeCASNo.：100-97-0危险性概述：HazardsIdentification：健康危害：生产条件下，主要引起皮炎和湿疹。皮疹多为多形性，奇痒，初起局限于接触部位，以后可蔓延，甚至遍及全身。HealthHazard:Themaincauseofdermatitisandeczemaduringproductionconditions.Skinrashesarepolymorphic,extremelytickle.Itstartswiththecontactingareathenspreadeventhroughoutthewholebody.急救措施:FirstAidMeasures:皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。Skin:RemovecontaminatedclothingandwashtheskinwithSOAPandwaterthoroughly.眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。就医。Eyes:Liftingtheeyelid,withflowingwaterornormalsalineflush.Seekmedicaladvice.吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。Inhalation:Rapidlyrunawayfromthesitetothefreshair.Keeprespiratorytractclear.Haveoxygentherapyifbreathingisdifficult.Takeartificialrespirationimmediately,ifbreathingstops.Seekmedicaladvice.食入：饮足量温水，催吐。就医。Ingestion:Drinkenoughwarmwaterandinducevomiting.Seekmedicaladvice.消防措施:FireFightingMeasures:危险特性：遇明火有引起燃烧的危险。受热分解放出有毒的氧化氮烟气。与氧化剂混合能形成爆炸性混合物。具有腐蚀性。Hazardcharacteristics:Itwillcauseburningifmeetswithfire.Heatdecompositionemitstoxicnitrogenoxidegas.Mixedwiththeoxidizercanformexplosivemixtures.Corrosive.灭火方法：喷水冷却容器，可能的话将容器从火场移至空旷处。Fireextinguishingmethods:Spraywatertocoolthecontainer.Movethecontainerfromthefirescenetotheopenairifpossible.灭火剂：泡沫、二氧化碳、雾状水、砂土。Extinguishingmedia:foam,carbondioxide,waterfog,sand.泄漏应急处理:AccidentalReleaseMeasures:应急处理：隔离泄漏污染区，限制出入。切断火源。建议应急处理人员戴防尘面具（全面罩），穿防毒服。不要直接接触泄漏物。Emergencyhandling:Leakageofcontaminatedareasshouldbeisolated,restrictedaccess,andcutoffthefiresource.Emergencypersonnelshouldwearadustmask(fullcover),andputanti-virusservice.Donothavedirectcontactwithleaks.小量泄漏：用洁净的铲子收集于干燥、洁净、有盖的容器中。Asmallleak:Collectinadry,cleanandliddedcontainerwithaclearshovel.大量泄漏：用塑料布、帆布覆盖。使用无火花工具收集回收或运至废物处理场所处置。Alargenumberofleaks:Coverthatbyplastictarpsandcanvas.Collectthatbynon-sparkingtoolsortransporttodisposalofwastedisposalsites.操作处置与储存:HandlingandStorage:储存注意事项：储存于阴凉、通风的库房。远离火种、热源。包装密封。应与氧化剂、酸类分开存放，切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有合适的材料收容泄漏物。StoreNote:Storeinacool,wellventilatedwarehouse.Keepawayfromfireandheat.SealedPackage.Shouldbestoredseparatelytooxidants,acidclassandavoidmixingstorage.TakeExplosion-prooftypelightingandventilation.Prohibitionoftheuseofmechanicalequipmentandtoolswhichareeasytoproducesparks.Storageareasshouldbeprovidedwiththeappropriatematerialtodealwiththeleakage.接触控制/个体防护:ExposureControls,PersonalProtection:工程控制：密闭操作，局部排风。Engineeringcontrols:Airtightoperations,localexhaustventilation.呼吸系统防护：粉尘浓度较高的环境中，佩戴自吸过滤式防尘口罩。必要时，建议佩戴自给式呼吸器。Respiratoryprotection:Inenvironmentswithhighdustconcentration,wearingaself-primingfiltertypedustrespirator.Ifnecessary,recommendswearingself-containedbreathingapparatus.眼睛防护：戴化学安全防护眼镜。Eyeprotection:wearchemicalsafetyglasses.身体防护：穿防毒物渗透工作服。Bodyprotection:Wearpoisoninfiltrationofoveralls.手防护：戴一般作业防护手套。Handprotection:Wearoperatingprotectivegloves.其他防护：工作现场禁止吸烟、进食和饮水。工作完毕，淋浴更衣。注意个人清洁卫生。Otherprotection:Nosmoking,eatinganddrinkingwater.Takeashowerandchangeclothesafterfinishingwork.Payattentiontopersonalhygiene.理化特性:PhysicalandChemicalProperties:外观与性状：白色细粒状结晶，味初甜后苦。AppearanceandOdor:Whitefine-granularCrystal,tastesweetearlyandbitterlater.熔点(℃)：263(升华)Meltingpoint(℃):263(sublimation)相对密度(水=1)：1.27Relativedensity(Water=1)：1.27燃烧热(kJ/mol)：239.7Heatofcombustion(kJ/mol)：239.7溶解性：溶于水、乙醇、氯仿、四氯化碳，不溶于乙醚、石油醚、芳烃。Solubility:solubleinwater,ethanol,chloroform,carbontetrachloride,notsolubleinether,petroleumether,andaromatichydrocarbons.主要用途：用作纺织品的防缩整理剂、亚氯酸钠漂白活化剂、防水剂CR的缓冲剂等。Mainuse:useasshrink-prooffinishingoftextiles,waterproofingagent,sodiumchloritebleachingActivatorCRBufferingetc.稳定性和反应活性：StabilityandReactivity：禁配物：强氧化剂、强酸。Banofdistribution:strongoxidizingagents,strongacids.毒理学资料：ToxicologicalInformation：急性毒性：LD50：9200mg/kg(大鼠静脉)LC50：无资料生态学资料：EcologicalInformation：废弃物性质：DisposalConsiderations:废弃处置方法：处置前应参阅国家和地方有关法规。建议用焚烧法处置。焚烧炉排出的氮氧化物通过洗涤器除去。DisposalMethod:Refertotherelevantnationalandlocalregulationsbeforedisposal.Incinerationmethodrecommended.Disposethenitrogenoxidefromincineratoremissionsbyscrubbers.运输信息:TransportationInformation:危险货物编号：41528Hazardousgoods#:41528UN编号：1328UN#:1328包装类别：O53PackageType:O53包装方法：螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱；螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶（罐）外满底板花格箱、纤维板箱或胶合板箱。PackingMethod:Thread-coveredglassbottles,iron-coveredglassbottles,plasticbottlesormetalbarrel(tank),Woodenboxes;threadedglassbottle,plasticbottleortinplatedsteelbarrel(tank),fullfloortakeaplywoodbox,fiberboardboxorboxes.法规信息：LawsandRegulations：国内化学品安全管理法规：化学危险物品安全管理条例(1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则(化劳发[1992]677号)，工作场所安全使用化学品规定([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志(GB13690-92)将该物质划为第4.1类易燃固体。Domesticregulationsonchemicalsafety:SafetymanagementofchemicaldangerousgoodsOrdinance(1987years2months17daysofStatepublishing)