搜索
高三化学检测试题共8页第-1-页化学试题81009010.522B30.5H1C12N14O16Cl35.5Fe56Cu64Ag108I127Pb207第Ⅰ卷（选择题，共40分）一．选择题本题共10小题，每小题2分，共20分。每小题只有一个选项符合题意。1A.“”B.“……”C.“()……”D.“”“,,”2A.B.C.“”D.3A.caB.N2(g)3H2(g)=2NH3(g)H92kJ•mol-1C.,1.25molNH35.6LD.ab高三化学检测试题共8页第-2-页4A2-B(CH3)2C(OH)C(CH3)32,2,3--3-C4D5SO2NOSO2NONa2S2O3NH4NO3(Ce)ANa2S2O4S+3B36g4NAH+(NAC24g10molCe4+DNH4NO36H2O2O2Cl2HClXCl2XABKICKSCNFeSO4DHNO3AgNO37AabBNa2CO3CDIII8CH2CHOCH3ababA36B48C46D412高三化学检测试题共8页第-3-页9ABCD4ml0.01mol/L,2ml0.1mol/L0.2mol/L5ml0.1mol/L5ml0.1mol/LCl2Br2I2AgClAgBrAgI10()3mol/LAgNO31mol/LAgNO3ABAgK1K2AK1K2B.K1K20.1mole-17.0gC.K2K1BD.,K2K1二、选择题本题共5小题，每小题4分，共20分。每小题有1个或2个选项符合题意，全都选对得4分，选对但不全的得1分，有选错的得0分。11.8XYZWr(X)r(Y)r(Z)WAYZ2B.XWC.XYZD.ZWXY1225Ag2CrO4CrO42-Ksp(AgCl)=1.810-10Aabc(Ag+)BAg2CrO410-12CAg2CrO425abD0.01mol/LAgNO320mL0.01mol/LKCl0.01mol/LK2CrO4CrO42-高三化学检测试题共8页第-4-页130.1mol/LH2C2O4H2C2O4HC2O4-C2O42-NaOHHClpHpH[a=1.35b=4.17Ksp(CaC2O4)=2.310-9]ApH=5c(C2O42-)c(H2C2O4)c(HC2O4-)BpKa=-lgKapKa2(H2C2O4)=4.17C0.1mol·L1NaHC2O4c(H+)=c(OH-)+c(C2O42)c(H2C2O4)DCaC2O4CaCl2c(C2O42-)c(Ca2+)14已知：R1COOR2＋R318OHR1CO18OR3＋R2OHAMl3BMlCDXYZ15AlCl31,2-60Br210%NaHCO3MgSO4MgSO4A1,2-BMgSO4C10%NaHCO3HClBr2D高三化学检测试题共8页第-5-页三、非选择题：本题共5小题，共60分。1610(NOCl)C12NONOCl():1Cl2______()2a→()F_________()3(NOCl)BNOX()K2____(“K1”“K3”)ZYZNOCl4Zmg250mL25.00mLK2CrO4cmol/LAgNO322.50mLAg2CrO4;Ksp(AgCl)=1.561010Ksp(Ag2CrO4)=11012(NOC1)()17122016NiO/TiO21TiO2Cl2TiO2+2C+2Cl2TiCl4+2CO________________________________________2NiO/TiO2_____________________________________________3CH3NH3+Ti4+Pb2+Cl-CH3NH3+HNHNH3HNH____________________________________________________________________高三化学检测试题共8页第-6-页4Sb()Ga()SbCl3GaCl3l:l____a.[SbCl2+][GaCl4-]b.[GaCl2+][SbCl4-]c.511abcd______a.b.c.d.________________62dpmg·cm-3____g·mol-1dNA1810.Ni①EH2-2e-=2H+E=0.00VCu-2e-=Cu2+E=0.34VFe-2e-=Fe2+E=-0.44VNi-2e-=Ni2+E=-0.25V②Ksp(NiS)=1.07×10-21Ksp(CuS)=1.27×10-361_________2①_________________________________________②___________________________3___________________________4pH2～5____________________________5NiSCu2+c(Ni2+)0.107mol·L-1c(Cu2+)__________mol·L-1高三化学检测试题共8页第-7-页19141NO2NO(g)+O2(g)2NO2(g)H2NO(g)N2O2(g)H10H2HH12T11L2NO2(g)2NO(g)+O2(g)I5minmol/Lmol/Lc(NO2)c(NO)c(O2)c(O2)I0.6000.2II0.30.50.2IIIIIa.1b.1c.13NO22NO2(g)N2O4(g)H0NO2N2O4(=)(NO2)=k1·P2(NO2)(N2O4)=k2·P(N2O4)k1k2kp()k1=_________________________4NH3NO4NH3+6NO=5N2+6H2On(NH3):n(NO)4:13:11:3NOaNO610-4mg·m-3AB0.8sNO_______mg·m-3·s-1bNH3NO_____5NOA_______________________________________NO____________________________________________高三化学检测试题共8页第-8-页2014.EPRABPC①RCOOR1R2OHΔ催化剂RCOOR2R1OH②(CH3)2C=CHCH3H2O2催化剂H2O③1FⅢ___________2C3Ⅳ4______DGHABCKMnO45E________①E②61111136