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1.5301[Co(en)(C2O4)]2-A.3B.4C.5D.62A[Co(ONO)(NH3)5]SO4IIIB[Co(NH3)5H2O]Cl3()C[PtCl(NO2)(NH3)4]CO3IVD[CrBr2(H2O)4]Br?2H2OIII3A.[Zn(NH3)4]2+B.[Co(NH3)6]3+C.[TiF4]-D.[Cr(NH3)6]3+4[Fe(CO)5]A.B.C.D.5[Cu(NH3)4][PtCl4]A.B.C.D.6A.B.C.D.7K3[FeF6]K3[Fe(CN)6]A.B.F-C.D.CN-8A.B.C.D.9[Ni(CN)4]-A.B.C.D.10Cl-Cl-A.[Co(NH3)4]Cl3B.[Co(NH3)4Cl3]C.[Co(NH3)4Cl]Cl2D.[Co(NH3)4Cl2]Cl11Al3+pH=56EDTAA.Al3+B.Ca2+C.Zn2+D.Ag+12A.MNMYB.MYMNC.MYMInD.MInMY13pH9NaFaThF=109.0aTh(OH)=104.7aY(H)=101.3=23.2A.2B.9.2C.12.9D.14.214A.B.C.pHD.pMFe3+Zn2+EDTAFe3+Zn2+A.B.C.D.16A.pHB.pHC.D.17EDTABi3Fe3A.B.KCNC.D.18ZnEDTAEDTAA.Pb(NO3)2B.Bi(NO3)3C.CdSO4D.CaCl219(In)EDTA(Y)M(X)(N)A.KNXKNYB.KNXKNYC.KMXKMYD.KMInKMX20AgBr=12.30[Ag(NH3)2]+=7.40AgBr1.001molL-1NH3molL-1A.10-4.90B.10-6.15C.0.10-9.85D.10-2.45(117)1[Mn(CN)6]4-(=1.73B.M.)_________[CoF6]3-(=4.90B.M.)_________2pH12EDTA_________MY___________3pH=1Bi3+Pb2+___________Bi3+Pb2+4Fe3+TFe3+EDTAFe3+T____________5TEDTAZn2+Fe3+Al3+_______________6H6InH2In4-Hin5-In6-(MIn)pH7EDTAZn2+Al3+Zn2+________________Al3+______Al3+8______________________9EDTACu2+pCu_________10KCNEDTAPb2+Zn2+Pb2+Zn2+,KCN11EDTApM_________________________________21212345631212AgBrKCNAg2S3Fe3+Bi3+lgKFeY=25.1lgKBiY=27.943+4+6+6+91[HgCl4]2-+4I-=[HgI4]2-+4Cl-2100mL0.10mol-1AgNO3NH32O200mLNH31molL-1Ag+([Ag(NH3)2]lg1=3.40lg2=7.40)350mL0.020molL-1Ni(NO3)2NH3NH4Cl100mLpH=10NH30.10mol-112EDTA3EDTANi2+[Ni(NH3)6]2lg1~lg62.754.956.647.798.508.49pH=10lgY(H)=0.45lgNi(OH)=0=18.674Ca2+Zn2+2.010-2mol-12.010-2mol-1EDTACa2+[CN-]=0.10mol-112Ca2+pHpH6.06.46.87.07.47.8lgY(H)4.654.063.553.332.882.47550mL0.01mol-110mol-130ml100mL120.0745g30.12g1.B2.A3.D4.C5.C6.C7.C8.D9.C10.D11.C12.D13.C14.B15.B16.D17.A18.B19.A20.D12345Fe3Al366.37[AlF6]3-8MInIn9101111Al3+EDTA2Al3+3Al3+234[PtCl2(NH3)2],[CoCl3(NH3)3]56F-CN-1=5.7810142=1+1c(NH3)+2c(NH3)2=2.5107=0.050molL-12.0109molL14.952+106.643+107.794+108.505+108.496=104.17=1.51042=18.670.45lg=14.05=1014.053c(Ni2+)=0.010molL1=-2+14.05=12.056Ni2+41Ca2+Ca2+pHYY(Zn)pM/=0.2,0.1Ylg(Y)max=lgK(CaY)8=10.698=2.69CN-Zn2+lg4=16.7Zn(CN)=1+4[CN-]4=1+1016.710-4.00=1012.7pH12OH-Zn2+[Zn2+]=Y(Zn)=1+K(ZnY)[Zn2+]=1+1016.5010-14.7=101.8YY(Zn)Ca2+2Ca2+pHpHY(H)=(Y)maxK(ZnY)[Zn]sp=102.69101.8=102.63pH=7.7pHCa(OH)2pKsp=5.19pH=14.00[pKsp+lgc(Ca)]=14.00[5.19+lg(2.010-2)]=12.25Ca2+pH7.7~12.255c(NH3)=0.932100018.2%17.0mol-1=9.98mol-1C(NH3)=9.9830100mol-1=2.99mol-1c(Ag+)=0.10050.0100mol-1=0.0500mol-11Ag++2NH3?[Ag(NH3)2+]+H2O/mol-1x2.99-0.100+2x0.0500-xx=5.3510-10mol-1c(Ag+)=5.3510-10mol-1,c(NH3)=2.89mol-1c[Ag(NH3)2]+=0.0500mol-12c(Cl-)=0.074574.5511mol-1=0.0100mol-1J=5.3510-100.0100=5.3510-12=1.7710-10AgClAgClc(Ag+)(1.7710-100.0100)mol-1=1.7710-8mol-1c(NH3)mol-1=0.502mol-13c(Br-)=(0.120119.000.1)mol-1=0.0101mol-1J=5.3510-100.0101=5.4010-12=5.3510-13AgBrAgBrc(Ag+)5.3510-130.0101mol-1=5.3010-11(mol-1)c(NH3)mol.L-1=9.18mol-123AgClAgBr