5环境法的主要制度2

ⅠⅡExperimentalⅢResultsⅠ:Soybean,Palm,Wasteoil,Rapseed,Jatropaetc.Animalfat:Lard,Tallow,Chickenetc.Marinebiomass:algaePalmSoybeanRapseedWasteoilJatropaLardTallowAlgae441.Introduction1.IntroductionBio-diesellawmaterials(78%)mostofthelawmaterialsforbio-dieselWeneedtofindbio-diesellawmaterialswhichcanbesuppliedinkoreaforenergysecurityAnimalfatisoneofthereasonablelawmaterialinkoreaforbio-diesel1.Introduction1.IntroductionThesituationofbio-dieselinkorea주1)Estimatedannualoccurringamountofanimalfat:RDA,BioenergyCropResearchCenter(2010.6.16.)2)Fattyacidyield:Lard(70%(min)~75%(max)),tallow(74%(min)~84%(max))3)Applyprospectamountrate20%(2011)and50%(2020)ofavailableanimalfat4)Volumeunit(1,000kL)(density0.89,Yield96%)050100150200250300350LardTallowAnimal’sinternalorgansBy-productofleatherBy-productofedibleoilrefineryanimalfat1,000tonestimatedannualoccurringanimalfatProspectof2011forBDProspectof2020forBDProspected183,200ton(198,000kL)in2020*Itisabout1%oftotaldieseluse(20millionkL)inkorea1.Introduction1.Introduction(‘09.6.18)HoldW.GtodiscussaboutpermissionofanimalfatBD(K-Petro)-NeedfordiversificationofBDrawmaterialsbuttheFAMEcontenttestmethodisnotexist(‘09.8.18)HoldqualitymanagementcommitteewithagendaofpermissionofanimalfatBD(K-Petro)-ApprovedpermissionofanimalfatBD※AddanimalfatforBDproductioninnotice(MKE2010-230)petroleumalternativefuel(‘10.7.22)HoldW.GaboutFAMEcontenttestmethodofanimalfatBD(K-Petro)-NeedtoreviewofprEN14103-2009asthetestmethodforanimalfatBD※DraftprEN14103,2009:Fatandoilderivatives-FattyAcidMethylEsters(FAME)-Determinationofesterandlinolenicacidmethylestercontents(‘10.9.~10.)PerformedinvestigationofprEN14103-2009(K-Petro)-DeterminedpossibilityofprEN14103-2009foranimalfatBDwhichcanbeappliedinkorea(‘09.6.18)HoldW.GtodiscussaboutpermissionofanimalfatBD(K-Petro)-NeedfordiversificationofBDrawmaterialsbuttheFAMEcontenttestmethodisnotexist(‘09.8.18)HoldqualitymanagementcommitteewithagendaofpermissionofanimalfatBD(K-Petro)-ApprovedpermissionofanimalfatBD※AddanimalfatforBDproductioninnotice(MKE2010-230)petroleumalternativefuel(‘10.7.22)HoldW.GaboutFAMEcontenttestmethodofanimalfatBD(K-Petro)-NeedtoreviewofprEN14103-2009asthetestmethodforanimalfatBD※DraftprEN14103,2009:Fatandoilderivatives-FattyAcidMethylEsters(FAME)-Determinationofesterandlinolenicacidmethylestercontents(‘10.9.~10.)PerformedinvestigationofprEN14103-2009(K-Petro)-DeterminedpossibilityofprEN14103-2009foranimalfatBDwhichcanbeappliedinkoreaProgressofintroducingtheanimalfatBD1.Introduction1.Introduction(prEN14103)foranimalfatBD-TheanimalfatBDisnotapplicableincurrenttestmethod(KSM2413,EN14103-2003)inkorea※TheanimalfatBDhasoddcarbonnumberFAME(C17)unlikevegetableBDusingainternalstandardmaterialincurrenttestmethodReviewoftheFAMEcontenttestmethod(prEN14103)foranimalfatBD-TheanimalfatBDisnotapplicableincurrenttestmethod(KSM2413,EN14103-2003)inkorea※TheanimalfatBDhasoddcarbonnumberFAME(C17)unlikevegetableBDusingainternalstandardmaterialincurrenttestmethod1.Introduction1.IntroductionReviewoftheFAMEcontentofanimalfatbio-dieselⅡ=EN14103-2003(Current)prEN14103-2009ScopeFAMEC14~C24*NotapplicabletoCoconut,Palm(C12FAMEismost)andAnimalfatBDFAMEC6~C24*ApplicabletoCoconut,PalmandAnimalfatBDInternalstandardMethylheptadecanoate(FAMEC17)Methylnonadecanoate(FAMEC19)ColumnPolyethyleneglycolstationaryphase(Carbowax20m,DBwax,CPwaxetc.)30m(L),0.35mm(I.D),0.25μm(filmthick)30m(L),0.25mm(I.D),0.25μm(filmthick)Temp.condition250℃(25min)60℃(2min)→10℃/min→200℃→5℃/min→240℃(7min)Flowrate1~2mL/min←Splitrate50mL/min100mL/minSample(10mLbase)Sample:250mgSTD:Take5mLof10mg/mL(Heptan)Sample:100mgSTD:100mgSolvent:tolueneprEN14103(2009):Fatandoilderivatives-FattyAcidMethylEsters(FAME)-Determinationofesterandlinolenicacidmethylestercontents↓FAMEanalysisPalmkerneloilSoybeanoilForverificationofpossibilityofvegetableoilBDanalysisWastecookingoilPalmoil2.FeedstockofBiodieselinkorea2.FeedstockofBiodieselinkoreaSecureBDsfortestSecureanimalfatBDsandvegetableoilBDswhichcanbedistributedinkorea←No.ofdoublebond→IncreaseHighCetannumberLowGoodOxidationstabilityBadBadColdperformanceGoodLowIodinevalueHigh3.QualitycharacteristicsofBD1003.QualitycharacteristicsofBD100FAME:063C10:054C12:044