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26520079ACTAPETROLOGICAETMINERALOGICAVol.26,No.5Sep.,2007综述与进展/王荔娟,胡恭任(,362021):,,,/,/:;/;;:P595;X142:A:10006524(2007)05045309Astudyofpollutiongeochemistryandpollutionpreventionmeasuresofmercuryinsoil/sedimentWANGLijuanandHUGongren(DepartmentofEnvironmentalScienceandEngineering,HuaqiaoUniversity,Quanzhou362021,China)Abstract:Inthispaper,theoriginsofmercuryandtheadvancesinthestudyofmorphologyandmorphologicalanalysisofmercuryarereviewed,andthemainfactorsthataffecttheadsorptionanddesorptionofmercuryarediscussed.Somemeasurestocontrolmercurypollutioninsoil/sediment,suchasbioremediation,reducingmercurypollutionfromemissions,areputforward.Theadvantagesandshortcomingsofseveralriskassessmentmethodsofmercurypollutioninsoil/sedimentarecomparedwitheachother,andtheprospectsofthestudyofgeochemicalbehaviorsofmercuryinsoil/sedimentarealsodealtwith.Keywords:mercury;soil/sediment;pollutiongeochemistry;pollutionpreventionmeasures1956,,,,,/(Bertoetal.,2006),,,/,//1,,:20070207;:20070508:(40673061);(D0310017):(1985),,,,Email:wlj625@hqu.edu.cn;:,Email:grhu@hqu.edu.cn,,:;!(,2002);∀;#(Wangetal.,2004),1/4(,2001;,2004):;!;∀;#,;∃(Wangetal.,2004;ChoongandKwang,2005)2,EhpH//,,%%(,2000;,2003;,2006),,,,(ICPMS),,,,Louise(1999),09pgHg,,AAS,,,HeBin(1998)SPMEGCMS,(AFS),10-9~10-12g/g,Lambertsson(2001)GCICPMS,,(HPLC),,,,(),(Westoo,1966)(2005)HPLCICPMS,10-12g/g,3/,,(Zhang,1993),,&∋(Vale,1998)/,,,(Papelisetal.,1995;Kaplanetal.,2000),,,,3.1,pH,pH3.1.1pHpHpH:;!;∀45426;#(,2002);∃(WuandLorreta,1998),pHHgpH,pHpH3~5,,H+,pH,,Hg[HgOH+Hg(OH)ClHg(OH)2](Yinetal.,1996)HgCl,Hg2+(pH6)Hg(OH)ClHg(OH)2,FepH,pH,,,pHHg(OH)ClHg(OH)2,Hg2+(,2003)pH,Hg2+(SOM)(,2001)3.1.2(SOM)SOMHg2+SOMSOM;SOM(Saneietal.,2005),(SaneiandGoodarzi,2006)Andersson(1979)(pH45~5),,SOMHg2+Hg2+pH,SOM,,Hg2+(,2001),Hg2+Hg2+,,(Hintelmannetal.,1995;Wallschlageretal.,1996)Benoit(2001)Ravichandran(1998),;,,(,1997),,,pH(,2000),,pH,3.1.3Hg2+,Cl-,Hg2+,Cl-/Hg2+,HgCl,Hg2+,Cl-Hg2+,Cl-Hg2+,,(HgC12);,Cl-Hg2+,Cl-Hg2+,Hg2+HgCl2,Cl-3.1.4:,;!,;,;∀,,,(YinYujun,1996);#,pH(1996),25(,;25(,3.2pH,:,,;!,pH,4555:/H+Hg2+(Veereshetal.,2003);∀Fe/MnFeMn,,,,,,FeMn,;#,;,,,,(Volesky,1990),,(),,(),,,,,,,,3.3(2006),()::SCs+VC=Q(1):Vdcdt=k1SC-k2VC(2)(1)(2):C=k1QV(k1+k2)+[Co-k1QV(k1+k2)]e-(k1+k2)t(3)C=C0e-(k1+k2)t+[1-e-(k1+k2)t]k1QV(k1+k2)(4)S(kg),V(mL),Cs(mg/kg),C(mg/L),Q(mg),k1(t-1),k2(t-1)(3)(4)pH,pH4//,/(,2000b;,2005)(,2005;,2006)(,2006;,2006)(,2005)(,2003)(PEF)(,1997;,2000a),,(k),,4,,,,,(,2003),,,(Fernandes,1997;,2000),,(,1999)(PEF),,,,,45626(,1997),,,,,,,,,,,,,,5,(SEF)AlTi,,,,,SEF,,,,AlTi,,,,,/,,,5,,,,,,(,1992),/,,:5.1,,,,,,,,,,,5.230%,,,,40%~82%(USEnvironmentalProtectionAgency,2002),,58%(USEnvironmentalProtectionAgency,1997)5.3,95)l0-6~100)l0-6,7000g,,,,,,,,,5.4,,4575:/,,,(,1996)MengHua(1998)Hg2+,,3500g/kg,34g/kg,5.5,,,,,5.6,,,,,,,,(,2004;,2005)6/,:(1)/(),(2),,,,(,1989)(3)/,,,(),(4)/,/,(5),/,,,Collasiol(2004)30%HNO3,,,,(6),kim(2006)(7)/,(AVS),AVS,(Peschetal.,1995)(8)/(2004)(),,(9),pHAVS,pH,;AVS,;,ReferencesAnderssonA.1979.Mercuryinsoils[A].TheBiogeochemiStryofMercuryintheEnvironment[C].Amsterdam:Elsevier,79~112.BeijingNormalUniversity.1992.InorganicChemistry(ThirdEdition)[M].Beijing:HigherEducationPress,814(inChinese).BenoitJM,MasonRP,GilmourCC,etal.2001.ConstantsformercurybindingbydissolvedorganiccarbonisolatesfromtheFloridaEverglades[J].Geochim.Cosmochim.,65:4445~4451.BertoD,GianiM,CovelliS,etal.2006.MercuryinsedimentandNassariusreticulates(GastropodaProsobranchia)inthesouthernVeniceLagoon[J].ScienceoftheTotalEnvironment,368:298~305.ChenCuihua,NiShijun,HeBinbin,etal.2005.AnassessmentofmineenvironmentalgeochemistryqualitybyGISmethodsinDex45826ing,Jiangxi,China[J].JournalofChengduUniversityofTechology(SCITechnolED),32(6):633~639(inChinese).ChenDengyun,LiuNaandZhangLanying.2005.Studyonspeciationanalysisofmercurybyhighperformanceliquidchromatographyinductivelycoupledplasmamassspectrometry[J].EnvironmentalChemistry,24(1):110~113(inChinese).ChenHuaiman.1996.MercuryPollutioninSoilPlantSystem[M].Beijing:SciencePress,206(inChinese).ChoongJeonandKwangHaPark.2005.Adsorptionanddesorptioncharacteristicsofmercury(II)ionsusingaminatedchitosanbead[J].WaterResearch,39:3938~3944.CollasiolA,PozebonDandMaiaSM.2004.Ultrasoundassistedmercuryextractionfromsoilandsediment[J].AnalyticaChimicaActa,518:157~164.DaiQianjin,FengXinbinandTangGuiping.2002.Thegeochemicalbehaviorofmercuryinsoilanditspollutioncontrol[J].GeologyGeochemistry,30(4):75(inChinese).DangMintuanandLiuJuan.2005.CurrentsituationandsolutionstoChinesemercurypollution[J].AppliedChemicalIndustry,34(7):395~396(inChinese).DengXiaohong.2003.Onspeciationanalysisofmercuryintheenvironment[J].JournalofWesternChongqingUniversity(NatureScienceEdition),2(3):42~45(inChinese).DingJianghua,WenYanmaoandShuQiang.2001.Studyonadsorptionandmethylationofmercuryinsoils[J].AgroenvironmentandDevelopment,1:34(inChinese).FangFengman,WangQichaoandHaoQingju.2001.Atmosphericmercury∗anoverviewofitssources,specification,andenviormentprocess[J].EnviormentHerald,(2):28~29(inChinese).FengMuhua,LongJiangping,YuLong,et