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1211.1160242.317000TS199A1000-4017200511-0045-04DevelopmentofelectrooxidationandelectroreductionmethodsfordyestuffeffluentstreatmentWangBin1GuanYujiang2YangWeishen11.LaboratoryofEnvironmentalElectrochemistrySchoolofEnvironmental&BiologicalScienceandTechnologyDalianUniversityofTechnologyDalian116024China2.DepartmentofEnvironmentalEngineeringTaizhouUniversityTaizhou317000ChinaAbstractTheelectrochemicalmethodhabeenapromiingwayforthetreatmentofwatewatercontainingdyetuff.Thiarti_cleummarizeandremarkthepreenttatuanddevelopmentoftheelectrooxidationandtheelectroreductionmethodinrecentyear.Andtheirexperimentmodetheelectrodematerialinelectrooxidationareevaluated.lntheendthepotentialdevelopmenttrendoftwomethodipointedout.Keywordsdyeingandfinihingwatewatertreatmentdecolorizationelectrooxidationelectroreduction0CODTOC12～51ClO-Fentondirectelectrooxidationindirectelectrooxidation1.11.1.12004-12-221980-20209187810111612～15galvanostaticconstantcurrent661719542005No.11$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$20activatedcarbonfiberACF0.6V1.1.219CE21PbO2F-PbO2/TiBi-PbO2/TiAg-Bi-PbO2/TiCo-Bi-PbO2/TiBCo-Bi-PbO2/Ti2.1VG.H.Chen13Boron-dopeddiamondBDDTi/BDDⅡ16GAC78162223ACF24～3124～30FentonFenton70%1.2ClO-FentonCl-32～36Cl-2237～39ClO-9Tak-HyunKim40Cl-Cl-Cl-3334384141Fenton2.8VCODFenton1H2O22Fe2+FeFe3+3H2OS.H.Lin42Fe2+H2O2FentonH2O2H2O243～46FentonFentonFeOH321920Pt/T.Bechtold1747501m3-1024PEPtOx/Ti10～50g/L85%642005No.11ávila-Jiménez48492859B3/123ACF%%%%%%%%1.J.199719619～21.2.J.20012184～7.3.J.199918129～32.4.J.20022255～7.5.J.2002285253～255.6.M.199527.7.J.200335152～55.8YaXiongPeterJ.StrunkHongyunXiaXihaiZhuKarlssonHansT.Treatmentofdyewastewatercontainingacidorangeiiusingacellwiththree-phasethree-dimensionalelectrodeJ.WaterResearch200135174226～4230.9.BJ.2003242108～111.10.J.20021856～9.11.BJ.200325942～45.12.-J.20002080～84.13ChenXuemingChenGuohuaYuePoLock.AnodicoxidationofdyesatnovelTi/B-diamondelectrodesJ.ChemicalEngineeringSci-ence200358995～1001.14AiminWangJiuhuiQuHuijuanLiuJiantuanGe.DegradationofazodyeAcidRed14inaqueoussolutionbyelectrokineticandelectrooxi-dationprocessJ.Chemosphere2004551189～1196.15.C..2000645～646.16.J.20045359～62.17BechtoldTBurtscherETurcanuA.Cathodicdecolourisationoftex-tilewastewatercontainingreactivedyesusingamulti-cathodeelec-trolyserJ.J.Chem.Technol.Biotechnol200176303～310.18Dávila-JiménezMMElizalde-GonzálezMPGutiérrez-GonzálezAPeáez-CidAA.Electrochemicaltreatmentoftextiledyesandtheira-nalysisbyhigh-performanceliquidchromatographywithdiodearraydetectionJ.JournalofChromatographyA2000889253～259.19.M.200123.20.ACFK.2004.21.PbO2J.2004181105～108.22LiFanFenglinYangWeishenYang.Performanceofthedecoloriza-tionofanazodyewithbipolarpackedbedcellJ.SeparationandPurificationTechnology20043489～96.23.J.200218434～36.24.ACFJ.199716419～25.25.J.199716524～27.26.J.199718689～93.27JinpingJiaJiYangJunLiaoWenghuaWangZijianWang.Treat-mentofdyeingwastewaterwithACFelectrodesJ.WaterResearch199933881～884.28.FentonJ.200034111531～1534.29ZheminShenWenhuaWangJinpingJiaJianchangYeXueFengAnPeng.Degradationofdyesolutionbyanactivatedcarbonfibere-lectrodeelectrolysissystemJ.JournalofHazardousMaterials200184107～116.30.J.20001221～25.31.J.2003252124～126.32VlyssidesAGLoizidouMKarlisPKZorpasAAPapaioannouD.ElectrochemicaloxidationofatextiledyewastewaterusingaPt/Tie-lectrodeJ.JournalofHazardousMaterials1999B7041～52.742005No.11$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$$33NaumczykJSzpyrkowiczLZilio-GrandiF.Electrochemicaltreat-mentoftextilewastewaterJ.Wat.Sci.Tech1996341117～24.34YANGCHLEECCWENTC.HypochloritegenerationonRu-Ptbi-naryoxidefortreatmentofdyewastewaterJ.JournalofAppliedE-lectrochemistry2000301043～1051.35VlyssidesAGPapaioannouDLoizidoyMKarlisaPKZorpasAA.TestinganelectrochemicalmethodfortreatmentoftextiledyewastewaterJ.WasteManagement200020569～574.36.J.1999195441～444.37Tak-HyunKimChulhwanParkJinwonLeeEung-BaiShinSan-gyongKim.PilotscaletreatmentoftextilewastewaterbycombinedprocessJ.WaterResearch2002363979～3988.38.J.200221485～88.39.X-BJ.199821270～71.40Tak-HyunKimChulhwanParkEung-BaiShinSangyongKim.EffectsofCl-basedchemicalcoagulantsonelectrochemicaloxidationoftextilewastewaterJ.Desalination200315559～65.41.BJ.20023512～14.42LinShengHChenMingL.Treatmentoftextilewastewaterbychem-icalmethodsforreuseJ.WaterResearch1997314868～876.43.J.20011831～4.44.J.200215116～19.45.J.200117457～60.46.FentonJ.20012472～76.47BechtoldTBurtscherETurcanuA.DirectcathodicreductionofLeucoSulfurBlack1andSulfurBlack1J.JournalofAppliedElectrochem1998281243～1250.48YasukiYoshidaetal.DecolorationofazodyeusingatomichydrogenpermeatingthroughaPt-modifiedpalladizedPdsheetelectrodeJ.ElectrochimicaActa199945409～414.49Cerón-RiveraMDávila-JiménezMMElizalde-GonzálezMP.Degra-dationofthetextiledyesBasicyellow28andReactiveblack5usingdiamondandmetalalloyselectrodesJ.Chemosphere2004551～10.50BechtoldTMaderCMaderJ.Cathodicdecolourizationoftextiledye-bathsTestswithfull-scaleplantJ.JournalofAppliedElectrochem-istry