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a1,2,1(11,200030;21,200335):,:;:X83012:A:100721504(2000)0320143209ApplicationofIonChromatographytoEnvironmentAnalysisZhengXiaohong1,ZhengXiaolin2,WangQin1(1.ShanghaiEnvironmentalMonitoringCenter,Shanghai200030;2.ShanghaiHongqiaoInternationalAirport,Shanghai200335)Abstract:Applicationofionchromatographytoenvironmentalanalysisanditscharacteristicswereintroduced,anditsfuturewasforecasted.Keywords:IonChromatography;Environmentalanalysis(IC)(HPLC),,,,,1Walters[1]AG9AS9SC,,,,0150LgöL,01999,Ag+Cl-Hautman[2]DionexIonpacAS9,NaOH-H3BO3,ClO2-ClO3-BrO3-Br-NO3--NNO2--N,3149147.38.32.41.4LgöL195nmClO2-BrO3-Br-NO3--NNO2--N,9141013716211211LgöL[3]F-Cl-NO2-Br-NO3-PO43-SO42-C2O42-,,,,,,[4]14320009AridEnvironmentalMonitoringVol.14No.3Sep..2000a:1999212229:(19662),,,,,,30(BrO3-ClO3-)F-Cl-NO3-NO2-SO42-Br-HPO42-,:217%,95%103%,,Chandramouleeswaran[5]AG4ASCAS4ASC,NaOHIto[6]TSKgelSAX,NaClO4-(pH6.1),(I-),,Cl-SO42-,012LgöL,9818%016%[7],217mmolöLNa2CO3+0.3mmolöLNaHCO3,,,9417%713%,717%,0105mgöL,,,Betti[8],Li+K+Mg2+Ca2+Na+,50Li+K+Mg2+Ca2+,2000Na+,012%212%Marr[9],130mgöLKadnar[10]IonPacAS9-SC,Na2CO3,Br-SO42-I-F-NO3-C2O42-PO43-,Br-SO42-I-011011012mgöLGros[11,12]F-Cl-NO3-NO2-SO42-Br-HPO42-,IonPacCS12,Li+Na+NH4+K+Mg2+Ca2+Sr2+,5%Pobozy[13]RP18,,205nm190nm()NO3-NO2-Cl-,200Ll,NO2-NO3-210LgöL115LgöL,,2Shotyk[14]Na+NH4+K+Mg2+Ca2+,(DionexOnGuardP),,Na+öNH4+100,Na+NH4+,1ngög[15]F-Cl-NO3-PO43-SO42-,0101701014010190106201053mgöL[16]Fe2+Fe3+Cu2+Zn2+4,öö,(EnH22+),DionexHPICCS2,,PAR,500nm,,,[17],,ICPAK,,Cl-NO2-Br-NO3-SO42-,44114,5110%,Cl-NO2-Br-NO3-SO42-0110183mgöL,Cl-LgöL[18,19]F-Cl-NO3-SO42-Li+Na+NH4+K+Ca2+Mg2+,,,,,,F-Cl-NO3-SO42-Li+Na+NH4+K+Ca2+Mg2+0.0100.0200.2500.5000.0200.0500.1000.2502.51.0mgöL,,,[20]F-Cl-NO2-PO43-Br-SO3-NO3-SO42-,10-610-9,3%,01994,501999,,215%(Na2CO3-NaHCO3)F-Cl-,[21],S(CAS)(),,,020mgöL,110-3mgöL,95%104%,,50mgöLFe2+Fe3+100mgöLCu2+1mgöLAl3+,pH1[22],,,(AOCI),:50200ml,(AOCI)281000LgöL,AOCI1664Lg,90%,10%,,[23],3(NO-2NNO3-NNH4+N),ö,HPICCS5,,:01999,015%,100%5%,(NO2-NNO3-NNH4+N),,[24],:019999,0128%,95%,010004mgöL,,,,NO2-N[25],-,Zn2+Pb2+Fe2+Mg2+Mn2+Cd2+Ca2+7,7,,:pH,,,93188%103.12%,Zn2+Pb2+Fe2+Mg2+Mn2+Cd2+Ca2+015100.10.30.210.1ng,Zn2+1100ng,Pb2+20200ng,Fe2+1100ng,Mg2+1100ng,Mn2+1200ng,Cd2+2200ng,Ca2+1100ng[26]5413SeO32-SeO42-F-Cl-NO2-NO3-SO42-7,SeO32-SeO42-,SeO32-SeO42-40LgöL50LgöL,,,SeO32-SeO42-,:F-85mgöLCl-60mgöLNO2-35mgöLNO3-20mgöLSO42-65mgöL,SeO32-SeO42-,Cl-SO42-,Ag+Cl-,Ba2+SO42-Cl-SO42-,[27]F-Cl-NO3-SO42-,,,F-Cl-NO3-SO42-0.0050.0150.0060.031mgöL,,,[28],TOYOPAKICSP,,,0101mgöL(NO3-),,,[29]F-Cl-NO3-NO2-PO43-BF4-,,015mgöL,8614%96.5%,Pospichalova[30],Cl-013LgöL[31]F-Cl-NO3-SO42-,,,[32]DionexOmniPacPAX-100,NaOH,,(PO43-P2O74-P3O105-),LgöL,97.49%106.83%,,[33]Cr(Ë)Cr(Î):Cr(Ë),CrO42-Cr(Î),520nmCr(Ë)Cr(Î),Cr(Ë)Cr(Î)30LgöL1LgöL,Cl-NO3-SO42-PO43-Ac-HCO3-Zn2+Pb2+Sn2+Mn2+Cd2+Co2+Al3+Cu2+,,Cr(Ë)Cr(Î)2Tanner[34][35]Cl-NO3-SO42-,,[36]S(Ì)S(Ì),HPLCAS4,Na2CO3-NaOH,H2SO4,,,S(Ì)028mgöL,64114,019995,S(Ì)01007mgöL,Na2CO3-NaOHTEA,S(Ì),S(Ì)6%,98%Oikawa[37]Cl-NO3-SO42-Na+K+NH4+Ca2+Mg2+,0.0050.0100.0250.0050.0100.0100.0050.010mgöLUdisti[38]LgöLF-,77ngöL440650ngöLBuck[39](ngög)Cl-NO3-SO42-Na+NH4+K+Ca2+Mg2+,,,Cl-NO3-SO42-Na+NH4+K+Ca2+Mg2+0.50.50.50.10.20.10.10.1ngög,[40]YSA,,F-,Cl-NO2-Br-NO3-PO43-SO42-,mgöLLgöL,213%,,Chang[41],0102LgöL[42],,,,214m3,210-4610-4110-3210-3ngöm3,2147%4.82%6.59%3.32%,92.9%99.3%91.0%101.7%95.6%96.7%91.7%99.2%,,84%,90%,,,,,Moskvin[43]KPS8PHFDabek-Zlotorzynska[44]4Li+Na+NH4+K+Rb+Cs+Mg2+Ca2+Sr+Ba2+F-Cl-NO2-Br-NO3-SO42-PO43-,,(IA)(GA)(GB)(CAT),,IACl-NO2-Br-NO3-SO42-PO43-0.040.020.030.030.020.040.06mgöL,GAF-Cl-NO2-Br-NO3-SO42-PO43-0.010.040.030.040.010.060.010.020.020.03mgöL,GBF-Cl-NO2-Br-NO3-SO42-PO43-0.0010.0050.0020.0050.0020.0060.0060.0040.0020.009mgöL,CATLi+Na+NH4+K+Rb+Cs+Mg2+Ca2+Sr+Ba2+0.0050.0250.0400.0100.0400.0500.0500.0500.0400.400mgöL[45]GCx501,,,,,,C1C57,,813%,90%,01010107mgöm3()Cassinelli[46]7413,01055mgöLCl-01215mgöLBr-,0106mgöL0116mgöL[47],,SO42-,,,011ngöL,[48]7F-Cl-NO2-PO43-Br-NO3-SO42-,Br-,3%(Br-)[49]F-Cl-NO3-SO42-,Na2CO3-NaHCO3,HPLCAS4,,,F-0.1017mgöL,Cl-0.31.0mgöL,NO3-01052.0mgöL,SO42-016110mgöL,F-Cl-NO3-SO42-31295.5612.3515.69mgöL,NO3-SO42-95.6%101.9%97.1%101.6%,,,,[50](TSP),2102%,01990,,3Shotyk[51],DionexMetpacCC1,HNO3,DionexTMC-1,HNO3,DionexIonPacCS-5,520nm,Cd013ngög[52]NaOH,,,,SO42-PO43-,,,,,24hSO2NOx2,,NS:,[53],NS,,:0109810-46.96010-4molöL,0112510-41.50910-4molöL,0.38010-43.04610-4molöL0.02710-41.24310-4molöL,0.01610-41.16810-4molöL,,,NS4,84114,[54],Shim-PackFe(Ë)Fe(Ê),,Fe(Ë)Fe(Ê)717LgöL318LgöL,Na+K+Ca2+Mg2+Cu2+Fe(Ë)Fe(Ê),,[55]YSAË,öö4:,0.280.500.120.18LgöL(As),,93.0%10718%Arar[56]Cr(Î),013014LgöL,pH7810,Cr(Ë)Cr(Ì)5,,,,(ICP-AES)(ICPMS)(FIA),,,,,:[1]WaltersBD,GordonG.AnIonChromatographicMethodforMeasuring5LgöLBromateIoninDrinkingWater[J].AnalChem,1997,69(20):42751[2]HautmanDP,BolyardM.AnalysisofOxyhalideDisinfectionby2productsandotherAnionsofInterestinDrinkingWaterbyIonchromatography[J].Chromatogr,1992,602(1ö2):65.[3],,,1[NO3-NO2-F-C2O42-][J]1,1993,11(4):3091[4],,1[J]1,1992,11(4):671[5]ChandramouleeswaranS,Vijaylak