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:025322409(2001)0320193208:2000212211;:2001203212:(19412),,,,.1,2(11,730060;21,030001):,,,,:;;;;:TQ533:A,,:(1);(2);(3);(4)(SCP);(5)(MTO)(MTG)20003803tPa3020tPa[13],,215%[1,4,5]2000240tPa,150tPa,220tPa[1],,[69],10tPa30tPa,2005340tPa,320tPa,260tPa[10]1,,,,[1],,,,19996,320tPa,Methanex2,97tPa,1999220061580tPa[1],,,Methanex9715tPa,100tPa,MetorSuperMethanol85tPa,TitanMethanol170tPa,,,1999[9],180,9tPa10,2tPa6tPa39,2tPa40GJ50GJ,7080,,,,80GJ,,,()H2PCOCO2CO2,29200136JOURNALOFFUELCHEMISTRYANDTECHNOLOGYVol129No13Jun12001©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[11,12]1[13]1,,200tPa,,,20052310tPa,30tPa60tPa[10];30tPa200860tPa120tPa1Table1TherelationofinvestmentandproductcostfortheinstallationofmethanolproductionfromcoalItemsReactorproductioncapacity104tPa3060120150240300Relativeinvestmentpertonproduct,%1008776726968Relativeproductcost,%100897976747324:(1);(2):(3):(4),1923BASFZnO2Cr2O3(30MPa),1965,1966,ICI,510MPa,200300,1972Lurgi2,70,(510MPa),,,(810MPa1510MPa),,ICI510MPa1010MPa,0133tPm3h015tPm3h016tPm3h;Lurgi810MPa,0180tPm3hICILurgi(MGC)ICI,510MPa1010MPa,,230270Lurgi510MPa1010MPa,,,,260MGC,,510MPa1510MPa,,CO(5),,:,MRF[14,15]SPC[16]GSSTFR(--)[17]RSIPR()[2];,Chem1SystemInc1[3,18],IFP[19],,49129©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(),,;,,Chem1SystemInc11975[20],90,,,5%15%H2P(CO+CO2)TexasLaporte,1997Kingsport715tPa,1998265d94d,,20%30%,,,2[18]2008200C3021000h,2Table2ComparisonoftwoprocessesformethanolproductionintechnologicaleconomyProcessesCH3OHcontentinoutletmolP%ThermalefficiencyP%CH3OHrelativeproductioncostRelativeinvestmentGasphasesynthesisprocess51086131100100Liquidphasesynthesisprocess14159719017177;,,,;,,,,,,,,90Berty[21](SolventMethanolProcess)SMP,,,,,[17,22],,,,CO,,;,,,11,CO90%,110tPht,,,,,,3[2,2326]:,(35040025MPa32MPa)80,,Cu2Zn2Al,ICI5121ICI5122ICI5123ICI5127,,ICI51275913:1©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:(a),CO,CO2,(b),,,(c),,,(d),,,,(e)10-7,ICILurgiICI,,,,,,,80ICI2,,,3140tPaLurgi,,,,,,,,Lurgi,,45tPaMHIMGC(SPC),,Lurgi,29KJPt,480tPa[16],,TECMFR2Z,75tPa85tPa150tPa,,14tPa,,,,[14,15]Topse,,012MPa013MPa,,,,,,,40,150tPa[7]DavyMchee75tPa[17,27],[28]CasaleLinde[27]69129©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(a),ICI75tPa,Lurgi45tPa(b),,LurgiLinde(c),,Lurgi,ICI(d),,LurgiLinde(e),(f),,TopseCasale(g),412Dexaco3000t4000t,450t800tDexaco,,,210MPa,410MPa,511MPa,20tPa,45%;10ft614MPaDexaco30tPa,;10tPa,Dexaco,[29,30],,,,Dexaco,70%,Shell(CO+H295%),,,,,,,,30tPa,Dexaco,:,90;,;,,:(1)1a,,,,,,,,,,,,,,,1Figure1Diagramoflarge2scalemethanolsynthesisreactors,,,,,,,,,(2)-1b,7913:1©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[31],,CO2(SINOPEC),,,[32]:MDEA30tPa,,43114GJ,10%15%,2,,SINOPECSINOPEC,:(1)2Figure2AnoptimalmethanolproductionprocessinChina,614MPa,,,60tPh,;(2),,;(3),,;,,,MDEA,;(4),43114GJ,,,,,,,,,,:(1),,;(2),89129©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(3)6(1),,,,,10%(2),,,,,,,,,,()(),()(),,,(3),,,C30220tPa,,,,,30tPa,,(4),,KELLOGGICIBRUANLUMUS,,,,SIN2OPEC,,(5),,,,,,,7(1),,(2)20tPa,170tPa,,,,200530tPa,200860tPa120tPa(3)Dexaco,,30tPa,,20tPa,(4),[1]1[J]1,2000,3:392431[2],1[J]1,2001,2:322351[3],1[J]1,1999,19(9):821119913:1©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[4]1()[J]1,2000,23:271[5]1()[J]1,2000,24:271[6]1[J]1,2000,21:222241[7],,,1()[J]1,2000,12:322351[8],,,1()[J]1,2000,13:332351[9]1[J]1,2000,20(7):1241[10]1[J]1,2000,6:182191[11]120tPa[J]1,1996,2:112151[12]120tPa[J]1,1996,21(5):302331[13]1[J]1,1986,2:582681[14]KunioHirotani1OptimumcatalyticreactordesignformethanolsynthesiswithTECMRF2Z\circledRreactor[J]1CatalysisSurveysfromJapan,1998,2(1):9921061[15],1(TEC)MRF[J]1,2000,2:6291[16]1[J]1,2000,38:621[17]121C1[J]1,2000,2:1251[18],,,1[J]1,1998,6:92151[19]PassGG,HolzhauserC,AkgermanA,etal1Methanolsynthesisinatricklebedreactor[J]1AIChEJ,1990,36:1054210601[20]SherwinMB,BlumDB1Methanolsynthesisinathree2phasereactor[J]1PrepPap2AmChemSoc,DivFuelChem,1975,120(3):14621511[21]KrishnanC,ElliottFRJr1,BertyJM1ContinuousoperationoftheBertyreactorforthesolventmethanolprocess[A]1AIChEAn2nualMeeting[C]1SanFrancisco,19891133e1[22],,,1[P]1ZL95115889191[23]1[J]1,1999,9:71[24]1C302[J]1,2000,25(4):342361[25],1C302[J]1,1998,23(3):432471[26]1C30220tPa[J]1,1998,23(2):382421[27],,1[M]1:,1991112122461[28],1[J]1,1999,1:492521[29]1[J]1,2000,8(8):2251[30],,1[J]1,2000,28(12):102131[31],1[J]1,1994,6:292341[32],,,1[J]1,1998,2:62101PERSPECTIVESONR&DINCOALC