曹 纬(,730050) ,、、、、。。。: 、、。,[1,2],,。1 [3],HelixchangerTM,ABB。,。ABB,。,“”。1/4,,。,(1a)。1b,,(a)(1c)。。,。(b)(c)1 a-;b-;c- :①;②。·50· 2000286,,1933,,,。:155; :(0931)2335931-2369(O)。,。,,。2 [4]Alares,BrownFin-tube。“”“”。,。40%,。,ASME。:,,,,,,。,。3 PACKINOX[5,6]PACKINOX,Secatnen,CacDregamont、。198110ElfDanges,CCR,4。、、87×104。,。,,2200t,3,。2 PACKINOX,CCR。PACKINOX2。,。,。,。,,。,。800m2,15000m2。10m2,,。(SUS321/347、SUS304L)。PACKINOX:、、,,,,。4 HiTRAN[7]CalGavinLtd.,Hitanmatrixelements,(Wire-fintubeinsets)。,、。,,,(3)。25()5()。。3 HiTRAN5 SRWTM[5]Hamon-Lummus。3~4·51·曹 纬 ,()(19×200mm)。,,4。,,,,,。4 SRWTM6 [8],,“”(шелевойзффекткипения),,(стесненныеусловияшелевыхканалов)。,。()。(5A)。,。,。,,,。,,。,,,。 A-1-();2-()B-a-; b-5 ,,,(1%~3%)。。(ΔT=1.9K)*35002000/3000/m1014/14/m1.8851.41/2.1/m 2.3282.32/2.32 0.280.28/0.286468/68130101/151/mm 1615/15 14.514/14*ΔT=1.9K;ΔT=1.2K。 ΔT≥1K,ΔT≥0.35K。7 [9]CarborundumCo.,HeatExchangerwithHexoloyRSiC,、。,。,204.4℃。。1 ..,1992,13(2):13.【56】·52· 20002865 ,,,:(1)。,,,。(2)。,6%[5],,。[6],,,,。,,。1 ,,..,1996.2 .——90.,1994,5(1):18.3 ,..,1996,2.4 PaulF,JacobsPhd.RapidPrototyping&ManufacturingFundamentalsofStereolithography.PublishedbySocietyofManufacturingEngineers.DeabomMI,1992.5 JacobsPF.StereolithographyandotherRP&MTechnologies.PublishedbySocietyofManufacturingEngineers,1996.6 ..,1988.【52】2 ,..,1999,20(4):25.3 KralD,StehlikP,VanDerPloecHJ,etal.HelicalBafflesinShell-and-TubeHeatExchangers,Part1:ExperimentalVarification.HeatTransferEngineering,1996,17(1):93.4 BrownFintubeCo.TwistedTubedoesmoreinthesamespace.CEP,1996,92(8):9.5 ,. と.[],1995,(3):44.6 ..,1999,29(2):35.7 DavidButterworth,MosconeCF.HeatTransferHeadsintothe21stCentury.ChemicalEngineeringProgress,1991,(9):30.8 познякВЕ,СавелъевВН.ИсследованиетеплопередачаИГцдровлическогоСопротивленияВВитыхконденсаторох-испарителяхизтруъокСдеформированнымореърением.Химическоеинефтегазовоемашиностроение,1997,(2):29.9 CarborundumCo.EnhanceyouheatexchangerwithHexoloyRSiC.ChemicalProcessing,1999,62(6):78.2001《》(2001,:4-669)(1999)390,20001《》《》。《》,。:CN31-1833/TQ;:ISSN1009-3281;:3101064000023;:4-669,()。《》,、、、、,,,。,1964200。《》,16,,,。《》:、、、、、、、、。《》2001,。。:3762211 :200040:(21)32140342×2416:(21)62489867 :tcedmci@public.sta.net.cn :·56· 2000286TheEffectsofDe-amineAftertheIonExchangewithNH+4ontheAcidity,StructureandDealuminumofZeoliteβZhaoYan,LiHua(InstituteofAnalyticalScience,NorthwestUniversity,Xi’an710032)YangXingbing,DuanXue(DepartmentofAppliedChemistry,BeijingChemicalUniversity)Theeffectsofde-amineaftertheionexchangeofNaβwithNH+4onthesurfaceacidityandstructureofZeoliteβandtheeffectsofcalcinationtemperatureonthedealuminationofNH+4βZeoliteframeworkwereinvestigatedusingPy-TPD,XRDandIR.Theresultsindicatethatde-amineathightemperatureleadstothesignificantdealuminationofβZeoliteframeworkandmigrationtosurfaceacidicsitesandresultsintheenrichmentofaluminumontheoutersurfacethanthebody,thedealuminationleadstothedecreaseofcatalystacidity;thehigherthede-aminetemperatureis,thelessertheacidamountandacidstrengthwillbe,LacidmainlyresultsfromthetetrahedralframeworkAl,theacidstrengthofthetetrahedralframeworkAlisstrongerthannonframeworkAl;Itisshownthatthecrystallinestructureandframeworkstructuredecreasewiththeincreaseofthecalcinationstemperature,inthede-amineprocessNH+4nearlyhasnosignificanteffectonthecrystallinityofβZeolite,buttheframeworkaluminumspecieswithNa+aremoredifficulttodetachfromtheframeworkthanthosewithNH+4;ThethermaldecompositionofNH+4isalsooneofthereasonscausingthedecreaseofcrystallinty.Keywords:Zeoliteβ,ionexchangewithNH+4,de-amine,alumination,surfaceacidity,crystallinityIntroductiononNewTypesofOverseasHeatExchangersCaoWei(LanzhouPetroleumMachineryResearchInstitute,Lanzhou730050)Newhigh-effectiveheatexchangersatabroadinlastedyears,forexample,Helixchanger,Twisted-tubeexchanger,Packinox,SRC,HiTRANheatexchangerwithHexoloySiCetal,areintroduced.Theperformanceandstructureofnewtypesofheatexchangesareoutlined.Developmentandapplicationofenhancedheattransferelementsaredescribed.Keywords:newtypeheatexchangers,heattransferperformance,enhancedheattransferStudyontheEffectofPhotocuringResinShrinkageonPartsCurlDistortionintheProcessofLaserRapidPrototypingDuanYugang,WangSuqin,ChenHao,LuBingheng(Xi’anJiaotongUniversity,Xi’an710068)ThephotocuringresinforLaserRapidPrototyping&Manufacturewasprepared,theshrinkagereasonsofphotocuringresinwasanalyzed,andtheeffectofthephotocuringresinshrinkageonpartscurldistortionwasstudied.Itmadealsoanexplanationonpartsdistortionphenomenonfromresinmicrostructureandcurlmechanism,andputforwardedmethodstoimproveitfromtheaspectsofresinandscantechnology.Keywords:LaserRapidPrototyping,photocuringresin,shrinkage,curldistortion·5·ABSTRACT