Agilent7700ICP-MS现场培训教材

Agilent7700ICPMSAgilent7700ICP-MSAgilent7700ICPMS7700ICP-MS:7700ICP-MS7700ICP-MS1:Agilent7700ICP-MS?ConcentricNebulizer()2?700KPa3.5%?40KPa20KPa3?;15-20?C230-400Kpa(3358PSI)?50mlIPA4?5-7m3/min(4.7-6.6m/s)Agilent7700SeriesAgilent7700ICPMS7700ICP-MSMassHunter:1PC2PC(password:3000hanover)3ICP-MS77004ICP-MSTopMassHunterICPMSAgilent7700ICPMS5InstumentInstrumentcontrolInstrumentcontrolVacuumvacuumonshutdownstandby***MetersMeterControlPanel5IF/BKPressure---AnalyzerPressure---TMPRevolutionWaterRF/WC/IFWaterTemperatureInletTempInternalTempS/CTemperatureForwardPowerReflectedPowerPlasmaFreqCarrierGasPressArGasTankPressCarrierGasMU/Dil.Gas/AuxGasAgilent7700ICPMS6MaintenanceReactionGasOpenBypassValve2-5ml/min5-10min;2ml/minAgilent7700ICPMS7STANDBY0.7Mpa,DIW()DIW8MaintenanceSampleIntroductionAgilent7700ICPMSInputsOutputsCloseSampleIntroductionMaintenanceAgilent7700ICPMS9InstumentcontrolPlasmaPlasmaONStandbyAnalysis****Standby2-5115-30ICP-MSTopTuneAgilent7700ICPMS21ppbDIWAcq.ParametersAcquisitionparametersAcq.Parameters789205156/140CeO/Ce70/140Ce2+/CePlotOKStartStopTestItemSpec.MassAxisLi(7)Y(89)Tl(205)0.1amu0.1amu0.1amuMassResolution(at10%)0.65-0.85amuSensitivity(0.1sec,1ppb)Li3000Y12000Tl6000Oxide(CeO/Ce)1.2%DoublyCharged(Ce2+/Ce)2.0%3//StartStop/Agilent7700ICPMS*****Acq.ParametersDisplayedtuneparameters41ppbTuneAutotuneTuningItemsP/AFactorRunAgilent7700ICPMSnogas.uHe.u,nogas.uHe.uHeCo30005618000CPS1.(ConcentricNebMiroMISTNeb):1500W0.9L/min(0.6~1.0L/min)0.25L/min(0.3~1.0L/min)8mm(7~10mm)0.1rps(0.1~0.2rps)2:7700NogasHe,H2,NogasH2,ArO,Ar2,ArHHe,NaAr,ClO,ArCl2.Agilent7700ICPMS2.1:Nogas(H2He)Extract100Extract2-180-200~-160OmegaBias-80-110~-70OmegaLens107~12CellEntrance-30-40~-30-40-40~-30CellExit-50-60~-40-60-60~-40Deflect108~150-5~4PlateBias-40-50~-30-60()OctopoleRF190100~200OctopoleBias-8-12~-6-18()QPBias-5-5~-3-15()He04.54~5H2065~7QPBiasOctopoleBias2~4evP/AFactorPAfactor(Sc(45),In(115),Tb(159),Bi(209)20-30ppb)Sc(45),In(115),Tb(159),Bi(209)40,000-400,000CountsTuneP/AFactorP/AFactorTuningLi(6)Sc(45)Y(89)In(115)Tb(159)Bi(209)Agilent7700ICPMSRunP/AFactorTuning?****DetectorParametersP/AFactor?****P/AFactorMergeinthecurrentdata****HePAFactor??AgilentCalibrationVerificationStandard(Part#5183-4682)EnvironmentalCalibrationStandard(Part#5183-4688,1000ppmFe,K,Ca,Na,Mg10ppmAg,As,Se,Cd,Pb,Ni,Cu,Zn)?-HNO3?-DI?-AgilentTuning1ppbLi,Co,Y,Ce,Tl??PAFactorPart#5183-4680,10ug/mLLi6,Sc,Ge,Y,In,Tb,Bi)200PAfactorTune(50ppbLi6,Sc,Ge,Y,In,Tb,Bi)1050ppb??1%HNO3CalibrationVerificationStandard(Part#5183-4682)EnvironmentalCalibrationStandard(Part#5183-4688,1000ppmFe,K,Ca,Na,Mg10ppmAg,As,Se,Cd,Pb,Ni,Cu,Zn)1000500STD1STD2??1ug/L2ug/LHg1%HNO3STD3STD4??1%HNO3STD0??1ug/mL(ISTD)------(Part#5183-4680,10ug/mLLi6,Sc,Ge,Y,In,Tb,Bi)??tapwater1%HNO3Agilent7700ICPMS1ICP-MSTopMethodsEditentiremethod2EditMethod3OKAgilent7700ICPMS4MethodCommentsThisistheEPA2008methodOK5SelectSampleTypeOK6InterferenceEquation,NogasEPA200_8,FOODORS,,OKAgilent7700ICPMS7AcquisitionModeSpectrumOKAgilent7700ICPMS8PeakPattern,FullQuant(3)PeriodicTable9ClearAll,ISTDNa,Mg,K,Ca,Fe,V,Cr,As,Cu,Ni,Zn,Hg,Pb,CdISTDSc,Ge,Y,In,Tb,Bi10OKAgilent7700ICPMS11SeteveryMassRepetition3IntegrationTime[sec]AsIntergrationtime1secEnterSe,Cd,Hg---2sec0.3sec12CheckParameterNoErrorOKerrorPeristalticPumpProgramAgilent7700ICPMS13PeristalticPumpProgramuptakespeed0.3rpsuptaketime30sec,stabilizationtime30secOK14OK,15EPA2008OK,1ISTD1ppmISTD1%HNO3TuningISTD(Ge,In,Tb,Bietc)RSD%5%2ICP-MSTopAcquireData,MainPanelAgilent7700ICPMS3AquireDataAquireData41%HNO3DIWblank.d,C:\ICPMH\1\DATA\DataFileNameOperatorName(User)DilutionFactor(1.00)(1%HNO3DIW)Acquire5Tabulate/Mass63----5STDAgilent7700ICPMSMassHunterAgilent7700ICPMS1DataAnalysisMainPanel...fileNewBatchFolderCreateAgilent7700ICPMS2DAMethodEditFullQuantAnalysisAgilent7700ICPMSISTDAgilent7700ICPMS4CurveFitOriginAgilent7700ICPMS5FullQuantOutlierAgilent7700ICPMS6ValidateOK7ReturntoBatch-at-aGlanceYes8FileImportSampleImportAllSampleFromBatchAgilent7700ICPMS9,OpenAgilent7700ICPMS10Type11CalBlkCalStdLevel12ProcessBatchAgilent7700ICPMS13ISTD14ReportgeneratereportAcrobatprofessionalPDF15Agilent7700ICPMS15%HNO35MinDIW5Min2ICP-MSTopICP-MSInstrumentcontrolPlasmaoffAnalysisStandbyStandby3StandbyICP-MSInstrumentcontrolVacuumVACUUMOFFStandbyShutdown4Shutdown5-105Ar6PC77700ICP-MSAgilent7700ICPMS123/4****13Agilent2